Diffusion-emission theory of photon enhanced thermionic emission solar energy harvesters

Numerical and semi-analytical models are presented for photon-enhanced-thermionic-emission (PETE) devices. The models take diffusion of electrons, inhomogeneous photogeneration, and bulk and surface recombination into account. The efficiencies of PETE devices with silicon cathodes are calculated. Our model predicts significantly different electron affinity and temperature dependence for the device than the earlier model based on a rate-equation description of the cathode. We show that surface recombination can reduce the efficiency below 10% at the cathode temperature of 800 K and the concentration of 1000 suns, but operating the device at high injection levels can increase the efficiency to 15%.Comment: 5 pages, 4 figure

Voltage modulated electro-luminescence spectroscopy and negative capacitance - the role of sub-bandgap states in light emitting devices

Voltage modulated electroluminescence spectra and low frequency ({\leq} 100 kHz) impedance characteristics of electroluminescent diodes are studied. Voltage modulated light emission tracks the onset of observed negative capacitance at a forward bias level for each modulation frequency. Active participation of sub-bandgap defect states in minority carrier recombination dynamics is sought to explain the results. Negative capacitance is understood as a necessary dielectric response to compensate any irreversible transient changes in the minority carrier reservoir due to radiative recombinations mediated by slowly responding sub-bandgap defects. Experimentally measured variations of the in-phase component of modulated electroluminescence spectra with forward bias levels and modulation frequencies support the dynamic influence of these states in the radiative recombination process. Predominant negative sign of the in-phase component of voltage modulated electroluminescence signal further confirms the bi-molecular nature of light emission. We also discuss how these states can actually affect the net density of minority carriers available for radiative recombination. Results indicate that these sub-bandgap states can suppress external quantum efficiency of such devices under high frequency operation commonly used in optical communication.Comment: 21 pages, 4 sets of figure

Heavy Meson Physics: What have we learned in Twenty Years?

I give a personal account of the development of the field of heavy quarks. After reviewing the experimental discovery of charm and bottom quarks, I describe how the field's focus shifted towards determination of CKM elements and how this has matured into a precision science.Comment: This talk was presented during the ceremony awarding the Medalla 2003 of the Division of Particles and Fields of The Mexican Phsyical Society, at the IX Mexican Workshop on Particles and Fields; submitted for proceedings; 9 pages, 9 figures; replacement: fix multiple typo

Experimental analysis of the thermal energy storage potential of a phase change material embedded in additively manufactured lattice structures

Recent literature introduced novel additively manufactured porous metallic structures designed to deliver enhancement of the thermal conductivity of organic phase change materials. Among these, so-called lattice structures are of particular interest for application in lightweight components. Originally investigated for their attractive mass-specific mechanical properties, these geometries were recently proposed, in alternative to metallic foams, as a conductive matrix of phase change materials. However, the geometrical parameters of a lattice structure differ from the ones of a metallic foam and no established data exist in the literature about the influence of the lattice cell geometry on the transient heat transfer enhancement of a phase change material. This work presents an experimental comparison of the thermal behaviour of a composite based on an n-Octadecane paraffin wax embedded in four different aluminium lattices with varying unit cell topology (f2ccz, bcc, bccz, f2bcc), but showing the same cell size, aspect ratio and strut diameter. It is noticed that the unit cell topology affects the transient thermal behaviour beyond its direct effect on the cell porosity. To address this, a specific thermal performance parameter is identified. The sample based on the f2ccz topology represents the best candidate. The influence of orientation with respect to gravity on the heat transfer is also investigated. While the samples show relatively low porosity, ranging from 70.7% to 83.4%, the wide pore diameters lead to a high impact of melt convection on the thermal behaviour of most samples. Up to 28% wall temperature variation is evidenced for different heating orientations

Deep levels in a-plane, high Mg-content MgxZn1-xO epitaxial layers grown by molecular beam epitaxy

Deep level defects in n-type unintentionally doped a-plane MgxZn1−xO, grown by molecular beam epitaxy on r-plane sapphire were fully characterized using deep level optical spectroscopy (DLOS) and related methods. Four compositions of MgxZn1−xO were examined with x = 0.31, 0.44, 0.52, and 0.56 together with a control ZnO sample. DLOS measurements revealed the presence of five deep levels in each Mg-containing sample, having energy levels of Ec − 1.4 eV, 2.1 eV, 2.6 V, and Ev + 0.3 eV and 0.6 eV. For all Mg compositions, the activation energies of the first three states were constant with respect to the conduction band edge, whereas the latter two revealed constant activation energies with respect to the valence band edge. In contrast to the ternary materials, only three levels, at Ec − 2.1 eV, Ev + 0.3 eV, and 0.6 eV, were observed for the ZnO control sample in this systematically grown series of samples. Substantially higher concentrations of the deep levels at Ev + 0.3 eV and Ec − 2.1 eV were observed in ZnO compared to the Mg alloyed samples. Moreover, there is a general invariance of trap concentration of the Ev + 0.3 eV and 0.6 eV levels on Mg content, while at least and order of magnitude dependency of the Ec − 1.4 eV and Ec − 2.6 eV levels in Mg alloyed samples

Generalized four-point characterization method for resistive and capacitive contacts

In this paper, a four-point characterization method is developed for resistive samples connected to either resistive or capacitive contacts. Provided the circuit equivalent of the complete measurement system is known including coaxial cable and connector capacitances as well as source output and amplifier input impedances, a frequency range and capacitive scaling factor can be determined, whereby four-point characterization can be performed. The technique is demonstrated with a discrete element test sample over a wide frequency range using lock-in measurement techniques from 1 Hz - 100 kHz. The data fit well with a circuit simulation of the entire measurement system. A high impedance preamplifier input stage gives best results, since lock-in input impedances may differ from manufacturer specifications. The analysis presented here establishes the utility of capacitive contacts for four-point characterizations at low frequency.Comment: 21 pages, 10 figure

Deconvolution of complex G protein-coupled receptor signaling in live cells using dynamic mass redistribution measurements

Label-free biosensor technology based on dynamic mass redistribution (DMR) of cellular constituents promises to translate GPCR signaling into complex optical 'fingerprints' in real time in living cells. Here we present a strategy to map cellular mechanisms that define label-free responses, and we compare DMR technology with traditional second-messenger assays that are currently the state of the art in GPCR drug discovery. The holistic nature of DMR measurements enabled us to (i) probe GPCR functionality along all four G-protein signaling pathways, something presently beyond reach of most other assay platforms; (ii) dissect complex GPCR signaling patterns even in primary human cells with unprecedented accuracy; (iii) define heterotrimeric G proteins as triggers for the complex optical fingerprints; and (iv) disclose previously undetected features of GPCR behavior. Our results suggest that DMR technology will have a substantial impact on systems biology and systems pharmacology as well as for the discovery of drugs with novel mechanisms

Comparing single-frequency bioelectrical impedance analysis against deuterium dilution to assess total body water.

Background/Objectives: In this study, we aimed to validate the accuracy of single-frequency bioelectrical impedance analysis (SF-BIA) at 50 kHz to assess total body water (TBW) against the reference technique deuterium dilution (D(2)O) and to explore if the simple clinical parameters extracellular fluid (ECF) composition and body shape explain individual differences between D(2)O and SF-BIA (Diff(BIA-D(2)O)). Subjects/Methods: We assessed TBW with D(2)O and SF-BIA in 26 women and 26 men without known disease or anomalous body shapes. In addition, we measured body shape with anthropometry and ECF composition (osmolality, albumin, glucose, urea, creatinine, sodium and potassium). Results: On group average, SF-BIA to predict TBW agreed well with D(2)O (SF-BIA, 39.8±10.1 l; D(2)O, 40.4±10.2 l; and Diff(BIA-D(2)O) -0.7 l). In four individuals ('outliers'; 15% of the study population), Diff(BIA-D(2)O) was high (-6.8 to +3.8 l). Diff(BIA-D(2)O) was associated with individual variations in body shape rather than ECF composition. Using gender-specific analysis, we found that individual variability of waist circumference in men and arm length in women significantly contributed to Diff(BIA-D(2)O). When removing the four 'outliers', these associations were lost. Conclusions: In the majority of our sample, BIA agreed well with D(2)O. Adjusting for individual variability in body shape by anthropometrical assessment could possibly improve the accuracy of SF-BIA for individuals who deviate from mean values with respect to body shape. However, further studies with higher subject numbers are needed to confirm our findings

Leptonic constant of pseudoscalar B_c meson

We calculate the leptonic constant for the ground pseudoscalar state of B_c meson in the framework of QCD-motivated potential model taking into account the two-loop anomalous dimension for the heavy quark current in the nonrelativistic QCD as matched with the full QCD.Comment: 6 pages, RevTeX4 file, 3 eps-figures, several references and remarks adde